Élaboration de nouveaux matériaux d’électrodes à base de polymères conducteurs et de complexes de manganèse-bases de Schiff

Abstract

In this work, we have synthesized Schiff base complexes and studied their electrochemical behavior. Also, modified electrodes are prepared by immobilization of the complex on organic matrices (polymers) and an inorganic matrix (montmorillonite of Maghnia). This material incorporated with the complex Mn (salen) has been the subject of an electrochemical study using a cavity microelectrode, which allowed us to confirm that the immobilization of the catalyst reduces the formation of catalytically inactive species. In addition, a new complex of Mn-tetradentate Schiff base was isolated and its structure determined by crystallography.